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Permeability analysis and seepage process study on crystal layer in melt crystallization with fractal and porous

Xiaobin JIANG, Baohong HOU, Yongli WANG, Jingkang WANG

《化学科学与工程前沿（英文）》 2011年 第5卷 第4期   页码 435-441 doi: 10.1007/s11705-011-1139-3

摘要： In this paper a porous media seepage model was applied to analyze the permeability and study the seepage process of crystal pillar formed in the preparation of electronic grade phosphoric acid (EGPA). By inspecting the seeping process, the structure parameter of crystal pillar could be obtained. Two basic ideal models (perfectly separated model and perfectly connected model) were presented and a characterized factor was introduced to modify the model. A good simulation result was obtained which met the experiment result well. The relationship between and permeability were also discussed. The characterized factor showed potential application on optimizing process.

关键词： melt crystallization     porous media     fractal     permeability     hyperpure material     simulation    

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冲击作用下多孔材料热力学特征的模拟与分析

许爱国,张广财,蔚喜军,潘小飞,朱建士

《中国工程科学》 2009年 第11卷 第9期   页码 13-19

摘要：

强冲击波的作用可在多孔材料中诱发复杂的时空耗散过程，在这期间系统整体处于远离平衡的状态，对这一过程的稳定模拟和结果分析均具有较强的挑战性。使用近期针对超高速碰撞而发展起来的物质点方法对这一过程进行模拟，引入积分几何和数值图像处理中的形态学描述来处理和分析系统热力学特征量例如温度的Turing斑图， 揭示出3个Minkowski泛函(白色区域相对面积、边界总长度、欧拉特征量)与系统中“高温区”所占份额、“热点”在空间的分布方式之间的对应，揭示出Minkowski泛函演化特征与冲击波及多孔材料相互作用过程之间的对应。研究了孔隙度和冲击波强度对物质状态参量的影响。

关键词： 冲击波     多孔材料     物质点法     形态学量度    

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Free vibration analysis of functionally graded porous curved nanobeams on elastic foundation in hygro–thermo–magnetic

《结构与土木工程前沿（英文）》 2023年 第17卷 第4期   页码 584-605 doi: 10.1007/s11709-023-0916-7

摘要： Herein, a two-node beam element enriched based on the Lagrange and Hermite interpolation function is proposed to solve the governing equation of a functionally graded porous (FGP) curved nanobeam on an elastic foundation in a hygro–thermo–magnetic environment. The material properties of curved nanobeams change continuously along the thickness via a power-law distribution, and the porosity distributions are described by an uneven porosity distribution. The effects of magnetic fields, temperature, and moisture on the curved nanobeam are assumed to result in axial loads and not affect the mechanical properties of the material. The equilibrium equations of the curved nanobeam are derived using Hamilton’s principle based on various beam theories, including the classical theory, first-order shear deformation theory, and higher-order shear deformation theory, and the nonlocal elasticity theory. The accuracy of the proposed method is verified by comparing the results obtained with those of previous reliable studies. Additionally, the effects of different parameters on the free vibration behavior of the FGP curved nanobeams are investigated comprehensively.

关键词： functionally graded porous material     curved nanobeam     hygro–thermo–magnetic     enriched finite element method    

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Iterative finite element model of nonlinear viscoplastic analyses for blended granular porous media

WU Yuching, ZHU Cimian

《结构与土木工程前沿（英文）》 2007年 第1卷 第4期   页码 464-473 doi: 10.1007/s11709-007-0063-6

摘要： The iterative finite element model, in which an element is used to represent a single particle, is generated to analyze the global behavior of multiple-material aggregates of materially nonlinear viscoplastic particles. The genera

关键词： nonlinear viscoplastic     iterative     behavior     multiple-material    

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Computational design of heterogeneous catalysts and gas separation materials for advanced chemical processing

Huaiwei Shi, Teng Zhou

《化学科学与工程前沿（英文）》 2021年 第15卷 第1期   页码 49-59 doi: 10.1007/s11705-020-1959-0

摘要： Functional materials are widely used in chemical industry in order to reduce the process cost while simultaneously increase the product quality. Considering their significant effects, systematic methods for the optimal selection and design of materials are essential. The conventional synthesis-and-test method for materials development is inefficient and costly. Additionally, the performance of the resulting materials is usually limited by the designer’s expertise. During the past few decades, computational methods have been significantly developed and they now become a very important tool for the optimal design of functional materials for various chemical processes. This article selectively focuses on two important process functional materials, namely heterogeneous catalyst and gas separation agent. Theoretical methods and representative works for computational screening and design of these materials are reviewed.

关键词： heterogeneous catalyst     gas separation     solvent     porous adsorbent     material screening and design    

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Performance of a bi-layer solar steam generation system working at a high-temperature of top surface

Jinxin ZHONG, Congliang HUANG

《能源前沿（英文）》 2023年 第17卷 第1期   页码 141-148 doi: 10.1007/s11708-021-0725-4

摘要： Many efforts have been focused on enhancing the vapor generation in bi-layer solar steam generation systems for obtaining as much pure water as possible. However, the methods to enhance the vapor temperature is seldom studied although the high-temperature vapor has a wide use in medical sterilization and electricity generation. In this work, to probe the high-temperature vapor system, an improved macroscopic heat and mass transfer model was proposed. Then, using the finite element method to solve the model, the influences of some main factors on the evaporation efficiency and vapor temperature were discussed, including effects of the vapor transport conditions and the heat dissipation conditions. The results show that the high-temperature vapor could not be obtained by enhancing the heat-insulating property of the bi-layer systems but by applying the optimal porosity and proper absorbers. This paper is expected to provide some information for designing a bi-layered system to produce high-temperature vapor.

关键词： solar steam generation     solar energy     numerical method     porous material    

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Fabricating sustainable lignin-derived porous carbon as electrode for high-performance supercapacitors

《化学科学与工程前沿（英文）》 2023年 第17卷 第8期   页码 1065-1074 doi: 10.1007/s11705-023-2313-0

摘要： Lignocellulosic biomass such as plants and agricultural waste are ideal to tackle the current energy crisis and energy-related environmental issues. Carbon-rich lignin is abundant in lignocellulosic biomass, whose high-value transformation and utilization has been the most urgent problem to be solved. Herein, we propose a method for the preparation of porous carbon from lignin employing an H3PO4-assisted hydrothermal method. We characterize the as-prepared lignin-derived porous carbon and investigate its potential for energy storage. After assisted hydrothermal treatment followed by carbonization at 800 °C, the lignin-derived porous carbon displays a high specific capacitance (223.6 F·g–1 at 0.1 A·g–1) and excellent cycling ability with good capacitance retention. In this present study, the resultant lignin-derived porous carbon was used as the electrode of a supercapacitor, illustrating yet another potential high-value use for lignin, namely as a candidate for the sustainable fabrication of main supercapacitor components.

关键词： lignin     porous carbon     electrode     supercapacitor    

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Optimized porous clay heterostructure for removal of acetaldehyde and toluene from indoor air

Pu ZHAO,Lizhong ZHU

《环境科学与工程前沿（英文）》 2016年 第10卷 第2期   页码 219-228 doi: 10.1007/s11783-014-0760-z

摘要： Adsorption is the most widely used technology for the removal of indoor volatile organic compounds (VOCs). However, existing adsorbent-based technologies are inadequate to meet the regulatory requirement, due to their limited adsorption capacity and efficiency, especially under high relative humidity (RH) conditions. In this study, a series of new porous clay heterostructure (PCH) adsorbents with various ratios of micropores to mesopores were synthesized, characterized and tested for the adsorption of acetaldehyde and toluene. Two of them, PCH25 and PCH50, exhibited markedly improved adsorption capability, especially for hydrophilic acetaldehyde. The improved adsorption was attributed to their large micropore areas and high micropore-to-mesopore volume ratios. The amount of acetaldehyde adsorbed onto PCH25 at equilibrium reached 62.7 mg·g , eight times as much as the amount adsorbed onto conventional activated carbon (AC). Even at a high RH of 80%, PCH25 removed seven and four times more of the acetaldehyde than AC and the unmodified raw PCHs did, respectively. This new PCH optimized for their high adsorption and resistance to humidity has promising applications as a cost-effective adsorbent for indoor air purification.

关键词： porous clay heterostructure     volatile organic compounds     adsorption     adsorbent     indoor air    

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Maximum entropy based finite element analysis of porous media

Emad NOROUZI, Hesam MOSLEMZADEH, Soheil MOHAMMADI

《结构与土木工程前沿（英文）》 2019年 第13卷 第2期   页码 364-379 doi: 10.1007/s11709-018-0470-x

摘要： The maximum entropy theory has been used in a wide variety of physical, mathematical and engineering applications in the past few years. However, its application in numerical methods, especially in developing new shape functions, has attracted much interest in recent years. These shape functions possess the potential for performing better than the conventional basis functions in problems with randomly generated coarse meshes. In this paper, the maximum entropy theory is adopted to spatially discretize the deformation variable of the governing coupled equations of porous media. This is in line with the well-known fact that higher-order shape functions can provide more stable solutions in porous problems. Some of the benchmark problems in deformable porous media are solved with the developed approach and the results are compared with available references.

关键词： maximum entropy FEM     fully coupled multi-phase system     porous media    

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S-enriched porous polymer derived N-doped porous carbons for electrochemical energy storage and conversion

Chao Zhang, Chenbao Lu, Shuai Bi, Yang Hou, Fan Zhang, Ming Cai, Yafei He, Silvia Paasch, Xinliang Feng, Eike Brunner, Xiaodong Zhuang

《化学科学与工程前沿（英文）》 2018年 第12卷 第3期   页码 346-357 doi: 10.1007/s11705-018-1727-6

摘要：

Porous polymers have been recently recognized as one of the most important precursors for fabrication of heteroatom-doped porous carbons due to the intrinsic porous structure, easy available heteroatom-containing monomers and versatile polymerization methods. However, the heteroatom elements in as-produced porous carbons are quite relied on monomers. So far, the manipulating of heteroatom in porous polymer derived porous carbons are still very rare and challenge. In this work, a sulfur-enriched porous polymer, which was prepared from a diacetylene-linked porous polymer, was used as precursor to prepare S-doped and/or N-doped porous carbons under nitrogen and/or ammonia atmospheres. Remarkably, S content can sharply decrease from 36.3% to 0.05% after ammonia treatment. The N content and specific surface area of as-fabricated porous carbons can reach up to 1.32% and 1508 m2·g−1, respectively. As the electrode materials for electrical double-layer capacitors, as-fabricated porous carbons exhibit high specific capacitance of up to 431.6 F·g−1 at 5 mV·s−1 and excellent cycling stability of 99.74% capacitance retention after 3000 cycles at 100 mV·s−1. Furthermore, as the electrochemical catalysts for oxygen reduction reaction, as-fabricated porous carbons presented ultralow half-wave-potential of 0.78 V versus RHE. This work not only offers a new strategy for manipulating S and N doping features for the porous carbons derived from S-containing porous polymers, but also paves the way for the structure-performance interrelationship study of heteroatoms co-doped porous carbon for energy applications.

关键词： porous polymers     porous carbons     sulfur and nitrogen doping     supercapacitor    

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Hierarchically porous materials: Synthesis strategies and emerging applications

Minghui Sun, Chen Chen, Lihua Chen, Baolian Su

《化学科学与工程前沿（英文）》 2016年 第10卷 第3期   页码 301-347 doi: 10.1007/s11705-016-1578-y

摘要： Great interests have arisen over the last decade in the development of hierarchically porous materials. The hierarchical structure enables materials to have maximum structural functions owing to enhanced accessibility and mass transport properties, leading to improved performances in various applications. Hierarchical porous materials are in high demand for applications in catalysis, adsorption, separation, energy and biochemistry. In the present review, recent advances in synthesis routes to hierarchically porous materials are reviewed together with their catalytic contributions.

关键词： hierarchically porous materials     synthesis     application    

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Boron and nitrogen co-doped porous carbon derived from sodium alginate enhanced capacitive deionization

《化学科学与工程前沿（英文）》 2023年 第17卷 第12期   页码 2014-2024 doi: 10.1007/s11705-023-2346-4

摘要： Capacitive deionization can alleviate water shortage and water environmental pollution, but performances are greatly determined by the electrochemical and desalination properties of its electrode materials. In this work, B and N co-doped porous carbon with micro-mesoporous structures is derived from sodium alginate by a carbonization, activation, and hydrothermal doping process, which exhibits large specific surface area (2587 m2·g‒1) and high specific capacitance (190.7 F·g‒1) for adsorption of salt ions and heavy metal ions. Furthermore, the materials provide a desalination capacity of 26.9 mg·g−1 at 1.2 V in 500 mg·L‒1 NaCl solution as well as a high removal capacity (239.6 mg·g‒1) and adsorption rate (7.99 mg·g‒1·min‒1) for Pb2+ with an excellent cycle stability. This work can pave the way to design low-cost porous carbon with high-performances for removal of salt ions and heavy metal ions.

关键词： capacitance deionization     porous carbon     B/N co-doping     heavy metal ions     water purification    

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The role of single deformed bubble on porous foam tray with submerged orifices on the mass transfer enhancement

《化学科学与工程前沿（英文）》 2023年 第17卷 第12期   页码 2127-2143 doi: 10.1007/s11705-023-2363-3

摘要： Foam trays with porous submerged orifices endow bubbles uniformly distributed, which are considered attractive column internals to enhance the gas-liquid mass transfer process. However, its irregular orifice and complex gas-liquid flow make it lack pore-scale investigations concerning the transfer mechanism of dynamic bubbling. In this work, the actual porous structure of the foam tray is obtained based on micro computed tomography technology. The shape, dynamic, and mass transfer of rising bubbles at porous orifices are investigated using the volume of fluid and continue surface force model. The results demonstrate that the liquid encroaching on the gas channels causes the increasing orifices velocity, which makes the trailing bubble easily detach from the midst of the leading bubble and causes pairing coalescence. Additionally, we found that the central breakup regimes significantly improve the gas-liquid interface area and mass transfer efficiency. This discovery exemplifies the mechanism of mass transfer intensification for foam trays and serves to promote its further development.

关键词： bubble formation     porous submerged orifices     process intensification     foam tray    

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An investigation on prevalent strategies for XFEM-based numerical modeling of crack growth in porous

《结构与土木工程前沿（英文）》 2021年 第15卷 第4期   页码 914-936 doi: 10.1007/s11709-021-0750-8

摘要： Crack growth modeling has always been one of the major challenges in fracture mechanics. Among all numerical methods, the extended finite element method (XFEM) has recently attracted much attention due to its ability to estimate the discontinuous deformation field. However, XFEM modeling does not directly lead to reliable results, and choosing a strategy of implementation is inevitable, especially in porous media. In this study, two prevalent XFEM strategies are evaluated: a) applying reduced Young’s modulus to pores and b) using different partitions to the model and enriching each part individually. We mention the advantages and limitations of each strategy via both analytical and experimental validations. Finally, the crack growth is modeled in a natural porous media (Fontainebleau sandstone). Our investigations proved that although both strategies can identically predict the stress distribution in the sample, the first strategy simulates only the initial crack propagation, while the second strategy could model multiple cracks growths. Both strategies are reliable and highly accurate in calculating the stress intensity factor, but the second strategy can compute a more reliable reaction force. Experimental tests showed that the second strategy is a more accurate strategy in predicting the preferred crack growth path and determining the maximum strength of the sample.

关键词： numerical modeling     extended finite element method     porous media     crack growth     stress intensity factor    

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Electrodeposited porous Pb electrode with improved electrocatalytic performance for the electroreduction

Jing WANG, Hua WANG, Zhenzhen HAN, Jinyu HAN

《化学科学与工程前沿（英文）》 2015年 第9卷 第1期   页码 57-63 doi: 10.1007/s11705-014-1444-8

摘要： A porous Pb foam was fabricated electrochemically at a copper substrate and then used as the cathode for the electroreduction of CO . The surface morphology and composition of the porous Pb electrode was characterized by scanning electron microscopy, X-ray diffraction, transmission electron microscopy and selected area electron diffraction. The honeycomb-like porous structure was composed of needle-like Pb deposits. Cyclic voltammetry studies demonstrated that the porous Pb electrode had better electrocatalytic performance for the formation of formic acid from CO compared with a Pb plate electrode. The increase in current density was due to the large surface area of the porous Pb electrode, which provides more active sites on the electrode surface. The improved formic acid selectivity was due to the morphology of the roughened surface, which contains significantly more low-coordination sites which are more active for CO reduction. The highest current efficiency for formic acid was 96.8% at -1.7 V versus saturated calomel electrode at 5 °C. This porous Pb electrode with good catalytic abilities represents a new 3D porous material with applications for the electroreduction of CO .

关键词： electrodeposited porous Pb     carbon dioxide     electroreduction     formic acid    

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标题 作者 时间 类型 操作

Permeability analysis and seepage process study on crystal layer in melt crystallization with fractal and porous

Xiaobin JIANG, Baohong HOU, Yongli WANG, Jingkang WANG

期刊论文

冲击作用下多孔材料热力学特征的模拟与分析

许爱国,张广财,蔚喜军,潘小飞,朱建士

期刊论文

Free vibration analysis of functionally graded porous curved nanobeams on elastic foundation in hygro–thermo–magnetic

期刊论文

Iterative finite element model of nonlinear viscoplastic analyses for blended granular porous media

WU Yuching, ZHU Cimian

期刊论文

Computational design of heterogeneous catalysts and gas separation materials for advanced chemical processing

Huaiwei Shi, Teng Zhou

期刊论文

Performance of a bi-layer solar steam generation system working at a high-temperature of top surface

Jinxin ZHONG, Congliang HUANG

期刊论文

Fabricating sustainable lignin-derived porous carbon as electrode for high-performance supercapacitors

期刊论文

Optimized porous clay heterostructure for removal of acetaldehyde and toluene from indoor air

Pu ZHAO,Lizhong ZHU

期刊论文

Maximum entropy based finite element analysis of porous media

Emad NOROUZI, Hesam MOSLEMZADEH, Soheil MOHAMMADI

期刊论文

S-enriched porous polymer derived N-doped porous carbons for electrochemical energy storage and conversion

Chao Zhang, Chenbao Lu, Shuai Bi, Yang Hou, Fan Zhang, Ming Cai, Yafei He, Silvia Paasch, Xinliang Feng, Eike Brunner, Xiaodong Zhuang

期刊论文

Hierarchically porous materials: Synthesis strategies and emerging applications

Minghui Sun, Chen Chen, Lihua Chen, Baolian Su

期刊论文

Boron and nitrogen co-doped porous carbon derived from sodium alginate enhanced capacitive deionization

期刊论文

The role of single deformed bubble on porous foam tray with submerged orifices on the mass transfer enhancement

期刊论文

An investigation on prevalent strategies for XFEM-based numerical modeling of crack growth in porous

期刊论文

Electrodeposited porous Pb electrode with improved electrocatalytic performance for the electroreduction

Jing WANG, Hua WANG, Zhenzhen HAN, Jinyu HAN

期刊论文